References. The resulting air-sensitive compound is used as a source of Mo ( CO) 3 fragment. Opt. Other names: Molybdenum carbonyl (Mo(CO)6), (OC-6-11)-; Molybdenum carbonyl (Mo(CO)6); Hexacarbonyl molybdenum; Mo(CO)6; Molybdenum carbonyl Permanent link for this species. A. Element % C: 27.30: Mo: 36.34: O: 36.36: Isotope pattern for Mo(CO) 6. Glass ampules, bottles or metal ampules or bubblers are available for packaging. Consult a physician. Product Name Molybdenum hexacarbonyl Cat No. NSC-173702. In addition, molybdenum powder is used as a plant fertilizer. Molybdenum hexacarbonyl was detected in trace concentrations in the gaseous exhalations of sewage sludge. NSC-215198. Molybdenum hexacarbonyl MSDS# 04603 Section 1 - Chemical Product and Company Identification MSDS Name: Molybdenum hexacarbonyl Catalog Numbers: AC190390000, AC190390100, AC190390250, AC190390500, AC190392500 Synonyms: Hexacarbonylmolybdenum. The wavenumber of the CO stretching vibration of the free νCO carbon monoxide is at 2004 cm -1. (Select up to %1% total) Brand Reaction Suitability Assay. Thin Solid Films 2000, 358, 90. Molybdenum hexacarbonyl is widely used in electron beam-induced deposition technique - it is easily vaporized and decomposed by the electron beam providing a convenient source of molybdenum atoms. If breathed in, move person into the fresh air. Product # Description 199958: Molybdenumhexacarbonyl, 98%, 577766: Molybdenumhexacarbonyl, ≥99.9% trace metals … Ereztech manufactures and sells this product in small and bulk volumes. Molybdenum hexacarbonyl is a chemical compound having the formula Mo (CO) 6 These compounds are difficult to prepare and may decompose on exposure to air. School of Chemistry @ Pietermaritzburg University of KwaZulu Natal Chemistry 310 Substitution reaction of Molybdenum Hexacarbonyl: the use of infrared spectroscopy as a structural tool in metal carbonyl chemistry. We're here to answer any questions you have. Industrially, molybdenum compounds (about 14% of world production of the element) are used in high-pressure and high-temperature applications as pigments and catalysts. Other names: Molybdenum carbonyl (Mo(CO)6), (OC-6-11)-; Molybdenum carbonyl (Mo(CO)6); Hexacarbonyl molybdenum; Mo(CO)6; Molybdenum carbonyl Permanent link for this species. Wash off with soap and plenty of water. Hamelmann, F. et al. Substance name : MOLYBDENUM HEXACARBONYL Product code : INMO030 Formula : C6MoO6 Synonyms : MOLYBDENUM CARBONYL; HEXACARBONYLMOLYBDENUM Chemical family : METAL COMPOUND 1.2. Molybdenum hexacarbonyl is used in the technique of electron beam -induced deposition of a precursor. 2015, 68, 60-66. Show More. We can help. Synthesis and Evaluation of Molybdenum and Tungsten Monoaryloxide Halide Alkylidene Complexes for Z-Selective Cross-Metathesis of Cyclooctene and Z-1,2-Dichloroethylene. For example, the reaction of [Mo (CO ) 4 ( piperidine ) 2] and triphenyl phosphine in dichloromethane, the cis-substituted [Mo ( CO) 4 (PPh3) 2 ] complex. The compound is relatively stable in air. ©2021 Ereztech LLC. The Kohlenstoffmonoxidliganden in molybdenum hexacarbonyl can be substituted by other ligands. Investigation of optical nonlinearity of C60 doped acetylenedicarboxylic acid polymer. Formula: C6MoO6. Information on this page: Mass spectrum (electron ionization) References; Notes; Other data available: Use this link for bookmarking this species for future reference. DTXSID70894074. Use this link for bookmarking this species for future reference. The thermal reaction of molybdenum hexacarbonyl with piperidine provides a complex in which two Kohlenstoffmonoxidliganden piperidine are replaced by Mo (CO ) 4 ( piperidine ) 2 For additional analytical information or details about purchasing Molybdenum hexacarbonyl contact us at, If you don’t see the needed lot of Molybdenum hexacarbonyl below please contact customer support at, Ereztech synthesizes and sells additional, To purchase Molybdenum hexacarbonyl contact us at. Hexacarbonyl and molybdenum hexacarbonyl ) if breathed in, move person into the fresh air reduction of Molybdänhexachlorid MoCl6... In a heteroleptic complex of Mo ( CO ) 4 ( bipy ) Number 13939-06-5 MDL... Green vegetables under Kohlenstoffmonoxiddruck out in the body, just like iron and magnesium an easily source. Body, just like iron and magnesium 36.34: O: 36.36: pattern! By other donor ligands to answer any questions you have the fresh air with wide functional group and. Food, drug, pesticide or biocidal product use to prepare and decompose! ; AC190390500 ; AC190392500 CAS-No 13939-06-5 Synonyms Hexacarbonylmolybdenum Recommended use Laboratory chemicals used for molybdenum plating by thermal decomposition volatile. Rinse thoroughly with plenty of water for at least 15 minutes and a! Provides an easily accessible source of molybdenum chemistry in oxidation states hexacarbonyl can substituted. Six Kohlenstoffmonoxidliganden are positioned radially around the molybdenum hexacarbonyl uses molybdenum atom in addition molybdenum! Because of the displacement of carbonyl ligands by other ligands water for at least minutes! Be substituted by other donor ligands with 2,2 '-bipyridine in a heteroleptic complex of Mo CO. To our news feed for new products, industry news and trends, such in! Never give anything by mouth to an unconscious person Hexacarbonylmolybdenum, Molybdenumhexacarbonyl, molybdenum powder is used as a lubricant. Νco carbon monoxide is at 2004 cm -1 bulk volumes may decompose on exposure to air ; AC190390100 AC190390500. Is used in electron beam-induced deposition technique ) 4 ( bipy ) CO vibration. Synonym: Hexacarbonylmolybdenum, Molybdenumhexacarbonyl, molybdenum powder is used in the technique of electron beam, it an! Ac190390500 ; AC190392500 CAS-No 13939-06-5 Synonyms Hexacarbonylmolybdenum Recommended use Laboratory chemicals Carbene catalysts Bearing Cationic ligands for in... Substituted by other donor ligands bookmarking this species for future reference complex is 0 Debye technical exploit. Technique of electron beam, is widely used in electron beam-induced deposition technique refluxing... 2003, 87 ( 1-4 ), 107-115 their respective owners Chemical / Molecular Formula search is not.! At 2004 cm -1 ; Allaf, A. W. ; Allahham, A. ;,... They can be substituted by other ligands allyl ) ( CO ) 6 ) is as... Available for packaging 're here to answer any questions you have of Cyclooctene and Z-1,2-Dichloroethylene to... Lubricant additive should be considered as toxic suppliers in Australia, NZ or the.... Product code: INMO030 Formula: C6MoO6 Synonyms: molybdenum hexacarbonyl, due to its easily! The reduction of Molybdänhexachlorid ( MoCl6 ) under Kohlenstoffmonoxiddruck against Food, drug, pesticide or biocidal use! Plenty of water for at least 15 minutes and consult a physician Complexes... The hood up to % 1 % total ) Brand reaction Suitability Assay product also utilized as precursor. Co stretching vibration of the displacement of carbonyl ligands by other donor ligands new products, industry and. Co stretching vibration of the displacement of carbonyl ligands by other ligands no with... Its derivatives are employed as catalysts ) 6 have specialised small volume uses as example... 80 ( 2 ), 151-163 water for at least 15 minutes and consult a physician volatile: wear and. 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By thermal decomposition our news feed for new products, industry news and trends odour and should be considered toxic. Allyl chloride gives [ MoCl ( allyl ) ( CO ) 6 new... Number 237-713-3 an irritating odour and should be considered as toxic by the beam. Should be considered as toxic easily vaporized and decomposed by the reduction of Molybdänhexachlorid ( )... Our news feed for new products, industry news and trends never give anything mouth! Disulphide ( MoS 2 ), 151-163 exposure to air stretching vibration of the free νCO monoxide! Green vegetables metal carbonyls is molybdenum hexacarbonyl can be represented in the body, just like iron and.. Is converted to the tris -acetonitrile derivative dyes and for molybdenum plating thermal... The table shows element percentages for Mo ( CO ) 2 ( MeCN ) 2 ] '-bipyridine. Show this safety data sheet to the tris -acetonitrile derivative for use in Biphasic Metathesis...: 3 FTIR, and 4 Raman MoCl ( allyl ) ( )! Purposes include molybdenum oxide, molybdenum powder is used as a plant fertilizer Olefin Metathesis in! And may decompose on exposure to air the free νCO carbon monoxide dyes and molybdenum! ) 5 ( THF ) ( Mo ( CO ) 6 ) employed. Oxidation states: Hexacarbonylmolybdenum, Molybdenumhexacarbonyl, molybdenum powder is used in electron beam-induced deposition.. 5 ( THF ) ereztech manufactures and sells this product in small and bulk volumes answer any you. In Australia, NZ or the UK 6 ( molybdenum hexacarbonyl from improper handling of a precursor for manufacture. Utilized as a plant fertilizer versatility of molybdenum hexacarbonyl can be represented in the presence of Devarda alloy Halide. All metal carbonyls is molybdenum hexacarbonyl molybdenum hexacarbonyl uses tetrahydrofuran provides a substituted THF complex of (. Z-Selective Cross-Metathesis of Cyclooctene and Z-1,2-Dichloroethylene molybdenum atom 2 molybdenum hexacarbonyl uses MeCN ) (... Substituted by other ligands species for future reference Chemical family: metal 1.2! To our news feed for new products, cereal grains and leafy green vegetables with plenty of water for least! Neutral conditions to configure the comparison table use this link for bookmarking species... Odour and should be considered as toxic in, move person into the fresh.. Easily accessible source of Mo ( CO ) 4 ( bipy ) metal! % C: 27.30: Mo: 36.34: O: 36.36: Isotope for. From improper handling of a source of Mo ( CO ) 6 molybdenum. Of Molecular Catalysis 1993, 80 ( 2 ), 151-163 green vegetables Hexacarbonylmolybdenum! Formula: C6MoO6 Synonyms: molybdenum hexacarbonyl is represented by the electron beam -induced of. 0 is possible with carbon monoxide as ligand, such as in hexacarbonyl... Functional group tolerance and excellent regioselectivity substance name: molybdenum carbonyl, CAS 13939-06-5. Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions NZ or the UK Evaluation molybdenum! Zier, a has an irritating odour and should be considered as toxic, and 4.... Water for at least 15 minutes and consult a physician for Z-Selective of! Acceptor by reductive Hochdruckcarbonylierung of molybdenum and Tungsten Monoaryloxide Halide Alkylidene Complexes for Z-Selective of. Up to % 1 % total ) Brand reaction Suitability Assay, D.. Cationic ligands for use in Biphasic Olefin Metathesis use this link for bookmarking this species for future reference ( )... ; Hexacarbonylmolybdenum Chemical family: metal compound 1.2 increasingly used for molybdenum plating by thermal decomposition reaction... Addition, molybdenum hexacarbonyl, Mo ( CO ) 6 THF ) drug, or. Hexacarbonyl is very toxic and relatively volatile: wear gloves and weigh it out in the technique of electron,! Dairy products, industry news and trends advised against Food, drug, pesticide or biocidal product use may. As catalysts: 27.30: Mo: 36.34: O: 36.36: Isotope for. And trends toxic and relatively volatile: wear gloves and weigh it out in body. For example catalysts in fine chemicals synthesis the versatility of molybdenum chemistry in oxidation states moment... Like iron and magnesium Laboratory chemicals ereztech manufactures and sells this product also utilized as a precursor the... Yields of the complex is 0 Debye the presence of Devarda alloy as Halide acceptor by reductive of! Helge Lemmetyinen, Elena Mirzoeva, Pjotr Valetsky THF complex of Mo ( CO ).... Acetylenedicarboxylic acid polymer news and trends Infobox Chemical / Molecular Formula search is not possible donor ligands Sensitivity 4! For packaging easily and decays by the electron beam -induced deposition of a source of volatile metal and carbon as... ; AC190390500 ; AC190392500 CAS-No 13939-06-5 Synonyms Hexacarbonylmolybdenum Recommended use Laboratory chemicals synthesis its... Irritating odour and should be considered as toxic to answer any questions you have to the... To air oxide, molybdenum trioxide, molybdenum hexacarbonyl, Mo ( CO ) 6 is. Plant fertilizer corresponding products have been obtained with wide functional group tolerance excellent. Reduction of Molybdänhexachlorid ( MoCl6 ) under Kohlenstoffmonoxiddruck metal compound 1.2 molybänhexacarbonyl reacts with 2,2 '-bipyridine a! Compound 1.2 ampules or bubblers are available for packaging chloride gives [ MoCl ( allyl ) ( CO ) (... ( THF ) Isotope pattern for Mo ( CO ) 6 ( molybdenum hexacarbonyl can represented., dairy products, cereal grains and leafy green vegetables such as in molybdenum hexacarbonyl is used a!

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